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How Particle Shape Influences Optical Properties of Pigments

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작성자 Leonora 작성일26-01-01 02:18 조회2회 댓글0건

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The form of pigment particles plays a essential role in determining their optical behavior, influencing how light is diffracted and ultimately affecting color appearance, lightness, opacity, and luster. While many assume pigment performance is governed mainly by formulation, the dimensional architecture of each particle can dramatically influence the way light is bounced, filtered, and transmitted. This is especially evident in industries such as industrial finishes, inkjet formulations, skincare products, and plastic resins, where appearance and durability are critical.


ball-shaped particles tend to scatter light uniformly in all directions, resulting in a muted, low-gloss look. This omnidirectional reflection reduces the strength of mirror-like shine, making surfaces appear duller. In contrast, sheet-like particles, such as those found in metallic flakes, pearlescent crystals, reflective micas, or glass platelets, arrange horizontally as the medium cures. These particles emit light along specific angles, producing brilliant reflective surfaces with shimmering tones. The alignment of such platelets strengthens direct light bounce, which is why they are widely used automotive paints and cosmetic formulations to achieve luminous visual impacts.


asymmetric particles, often generated through mechanical grinding, introduce a wider angular distribution of reflected light. This diversity can enhance hiding power by trapping light through scattering events and light path elongation within the pigment layer. However, it may also reduce saturation and subdued coloration, because the light is deflected erratically. In contrast, synthetic pigments with consistent, anisotropic geometries—like needle-like, cubic, and branched forms—can be calibrated to direct photon behavior, increasing color purity and chroma.


Particle shape also affects aggregate structure and surface uniformity. round particles can form tighter arrays, eliminating air pockets and strengthening resistance to permeation, but they may demand increased dosage to achieve the equivalent hiding power as lamellar particles. lamellar pigments, because of their large surface area and planar structure, can overlap and form a continuous barrier with minimal loading, leading to improved hiding power at decreased用量. This efficiency translates to lower material use and greater longevity in commercial coatings.


Furthermore, the aspect ratio—the ratio of a particle’s length or diameter to its thickness has immediate consequences for reflective quality. High aspect ratio particles, such as highly anisotropic crystals, focus specular output and light polarization phenomena. They are highly effective in applications requiring eye-catching finishes, like tamper-evident inks and chromatic coatings. Conversely, nearly equiaxed shapes, which are close to cubic or spherical, provide even chromatic response and are recommended in applications demanding consistent, non-metallic appearances.


Manufacturers now use precision engineering such as nano-milling, solution-based nucleation, and epitaxial growth to engineer morphology deliberately. These methods allow for the manufacture of chromatic particles with engineered shapes that fulfill performance criteria. For instance, inorganic colorants can be formed into close-to-round morphologies to optimize coverage in dispersions, or aligned as nanoscale sheets to improve UV scattering in topical products.


In summary, particle shape is not a secondary characteristic in pigment development. It fundamentally controls how light reflects, absorbs, and transmits through the medium, shaping the final visual outcome. Harnessing particle geometry enables the creation of pigments with tailored optical properties, transforming color into experience to the designing dynamic light interactions. As methods evolve, 粒子径測定 the capacity to control morphology at microscopic levels will continue to unlock new possibilities in optical engineering and surface science.

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